As others mentioned, probably a mixture of really dank fungus, rotted tree bark, dried blood, oil, and gun-smoke.
for whatever reason, i think orks smell like cabbage gunpowder and oil. o and cigar smoke, lots of cigar smoke.
Imagine...heaven except its not heaven and its green and it has two legs. BUT it also has a small butt, butt thats okay because THEY HAVE BIG AXES AND STUFF but Up close you smell the smell of green and dirty flowers and then you realize you're actually playing world of warcraft Wait what was the question again?
Whatever is in da Squig drops. Every ork takes a trip to the drops at least once a day, so they always wind up smelling like whatever's in the drops.
Da 'ell is wiv all dese 'umies invadin dis fread? To a human, they probably smell really bad. Evil Sunz, not as much, because they probably smell mostly like smoke and gas (not THAT gas, I mean the fuel gas).
A proppa' Ork should smell like Dakka! n nuffin' more. Fuel like smell, accompanied by Blood and Gunpowder. And perhaps abit of Roses in the morning from the fungus.